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Polybutadiene Rubber

Polybutadiene rubbers are highly elastic and have a very high degree of resistance to dynamic stress, and retain these properties even at extremely low temperatures. Blending natural rubber or styrene butadiene rubber with Buna CB improves the abrasion resistance, crack resistance and heat build-up under dynamic load.
Butadiene rubbers are produced by the solution polymerization process with the aid of organometallic catalysts. The catalyst system, which is characterized by the particular metal (neodymium, cobalt, lithium or titanium), influences the microstructure and macrostructure of the polymers and therefore the properties. LANXESS currently produces Nd, Co and Li grades.


The neodymium (Nd) catalyst system gives a polymer structure that cannot be obtained with other catalysts and which enables marked improvements in vulcanizate performance to be achieved. The Nd-BR grades have the highest cis-1,4 content, a relatively low molecular weight distribution and a low degree of branching.

The high-cis BR grades based on Nd, Co and Ti catalysts differ in cis-1,4 content, low-temperature crystallization behaviour and glass transition temperature. Ti-BR contains slightly less cis-1,4 than the Nd and Co grades and therefore has a higher crystallite melting temperature and slightly higher glass transition temperature. Where these microstructural properties are concerned, the Co-BR grades are intermediate between the Nd and Ti grades. The macrostructure of Co-BR is distinguished by a moderately broad molecular weight distribution and medium degree of branching.


Catalystcis 1,4trans 1,4vinyl 1,2Tg (DSC)
Nd>962<1-109
Co9622-107
Li385210-93
Ti19244-105
1not in product range, included for comparison

Golf balls produced with NdBR



The Li-BR grades have a medium cis-1,4 content and a considerably higher glass transition temperature, and are entirely amorphous. These grades have a very narrow molecular weight distribution and low degree of branching.

NamePlantTypeML 1+4RemarkTDSMSDS
Buna CB 21DormagenNd-BR73highly linearTDSMSDS
Buna CB 22Dormagen / Pt. Jérôme / OrangeNd-BR63highly linearTDSMSDS
Buna CB 23Dormagen / OrangeNd-BR51linearTDSMSDS
Buna CB 24Dormagen / Pt. Jérôme / OrangeNd-BR44linearTDS

MSDS
Buna CB 25Dormagen Nd-BR44long chain branchedTDSMSDS
Buna CB 29 MESDormagen Nd-BR37oil extendedTDSMSDS
Buna CB Nd 40CaboNd-BR41,5linearTDSMSDS
Buna CB Nd 40 HCaboNd-BR44linearTDSMSDS
Buna CB Nd 60CaboNd-BR63linearTDSMSDS
Buna CB 55 NFPt. JérômeLi-BR55linearTDSMSDS
Buna CB 60Pt. JérômeLi-BR60star branchedTDSMSDS
Buna CB 45 BCaboLi-BR45linearTDSMSDS
Buna CB 55 BCaboLi-BR55linearTDSMSDS
Buna CB 55 HCaboLi-BR54linearTDSMSDS
Buna CB 55 LCaboLi-BR51linearTDSMSDS
Buna CB 70 BCaboLi-BR70linearTDSMSDS
Buna CB 1220OrangeCo-BR40branchedTDSMSDS
Buna CB 1221OrangeCo-BR53branchedTDSMSDS
Buna CB 1203OrangeCo-BR43branchedTDSMSDS
Buna CB 45OrangeLi-BR45linearTDSMSDS



Typical applications are tires, conveyor belts, caterpillar tread blocks, footwear soles, V-belts; they can be blended with NR for goods having thick sections and needing high resistance to reversion, e.g. buffers, roll covers needing high abrasion resistance; seals, profiles and other goods, particularly those produced by injection molding. Provided that the compounds are formulated and processed correctly, the vulcanizates have good resistance to aging, reversion, abrasion and flex cracking, good low temperature flexibility and high resilience.



Key Properties

- good resistance to aging and reversion
- excellent abrasion resistance
- low dynamic fatigue resistance
- good low-temperature flexibility
- high resilience


Food contact

Information concerning FDA and BfR compliance can be obtained on request from the Health, Safety, Environment and Quality Department (HSEQ) of Lanxess.

_Data Sheets_Buna CB